Mid-Infrared Reflectance Studies of Mercury Surface Regolith Analogs

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Abstract

Introduction: The IRIS (Infrared and Raman for Interplanetary Spectroscopy) laboratory generates mid-infrared spectra for a database for the ESA/JAXA BepiColombo mission to Mercury. Onboard is a mid-infrared spectrometer (MERTIS-Mercury Radiometer and Thermal Infrared Spectrometer), which will allow to map the mineralogy in the 7-14 µm range [1, 2]. In order to interpret the future data, a database of laboratory spectra is assembled at the Institut für Planetologie in Münster (IRIS) and the DLR in Berlin. Synthetic analogue materials have become one of the foci of our work, since they allow to produce ‘tailor-made’ materials based on remote sensing data and/or modelling and experiments. These are closer than natural terrestrial materials, which formed usually under different conditions as expected on Mercury [e.g. 3].
Here, we present the new infrared data of mineral and glass mixtures based on the compositions according to recent laboratory experiments [4], that studied melting of hermean mantle at high pressures, high temperatures and appropriate oxygen fugacities. These experiments suggested that the hermean surface mineralogy should be dominated by variable abundances of plagioclase, olivine, clino- and orthopyroxene, with unconstrained proportions of silicate glass. 
Based on the model mineralogy of representative results, we produced mineral/glass mixtures based on the Low-Mg Northern Volcanic Plains (NVP)(Y121, Y131, Y172), High-Mg NVP (Y143, Y144), Smooth Plains (Y140, Y143, Y144), Inter crater Plain and Heavily Cratered Terrains (IcP-HCT) (Y126, Y131, Y132, Y146), and High-Mg Province (Y126, Y131, Y146) [4].

Samples and Techniques:
We conducted diffuse reflectance studies of sieved size fractions (0-25 µm, 25-63 µm, 63-125 µm and 125-250 µm) under vacuum conditions, ambient heat, and variable geometries. We used a Bruker Vertex 70v with A513 variable geometry stage. The results will be made available in the IRIS Database [1].
Results:
First results show the Christiansen Feature (CF), a characteristic, easy to identify reflectance low (or emission high) ranging from 7.9 µm to 8.2 µm (always average of all size fractions). The Transparency Feature (TF), typical for the finest size fraction (0-25 µm) is in many mineral mixtures less pronounced than for pure mineral phases. Here the individual TF of the components result in a broad feature. 

Outlook:
In a next step, we will study these mixtures under more realistic conditions, i.e., high vacuum and high temperature, in order to better simulate the hermean surface. Also, these mixtures will be used to test spectral unmixing routines, which allow to identify abundances of single minerals in a complex mixture of phases. 

References: [1] Hiesinger et al. (2020) Space Sci. rev. 216, 110 [2] Benkhoff et al. (2022) Space Sci. Rev. 217, 90 [3] Morlok et al. (2021) Icarus 361, 114363 [4] Namur and Charlier (2017) Nature Geosci. 10, 9-13